Publication Date:
2012
abstract:
In the presence of the sodium salt of a bulky anion, which allows the solubility of Na+ in low polarity solvents, various tetra(4-pyridyl)porphyrin derivatives can spontaneously self-assemble from CH2Cl2 into supramolecular nanostructures exhibiting a long-range order, through the coordination of Na+ ions by the pyridyl moieties at the macrocycle periphery.
Iris type:
14.a.1 Articolo su rivista
Keywords:
porphyrins; self-assembly; N-Coordination; Thin solid films; nanocrystalline materials
List of contributors:
Mariachiara Trapani;Maria Rosaria Plutino;Giuseppe Sabatino;Ilaria Occhiuto;Anna Borriello;Giovanna De Luca;Luigi Monsu' Scolaro
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