Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin–Calixarene Assemblies
Academic Article
Publication Date:
2020
abstract:
The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.
Iris type:
14.a.1 Articolo su rivista
Keywords:
calixarenes, chirality induction, circular dichroism noncovalent interactions, porphyrinoids
List of contributors:
Gaeta, M.; Sortino, G.; Randazzo, R.; Pisagatti, I.; Notti, A.; Fragala, M. E.; Parisi, M. F.; D'Urso, A.; Purrello, R.
Published in: