Wet air oxidation of p-coumaric acid over promoted ceria catalysts

The catalytic wet air oxidation (WAO) of p-coumaric acid (PCA) has been investigated over Fe- and Zn-promoted ceria catalysts. The catalysts have been prepared by the coprecipitation method and have been characterized by X-ray diffraction (XRD), BET surface area, SEM-EDX and temperature programmed reduction (TPR). The oxidation reaction was carried out in a batch reactor under an air pressure of 2 MPa and in the temperature range 353-403 K. Fe-CeO2 catalysts, with 20-50 mol% of iron, were found more effective than the unpromoted and Zn-promoted ceria catalysts. On the basis of characterization data, it has been suggested that the higher activity of the Fe-promoted catalysts is related to the modification of the structural and redox properties of the ceria oxide catalyst on addition of iron. (C) 2002 Elsevier Science B.V. All rights reserved.