Data di Pubblicazione:
2016
Abstract:
We study the self-diffusion coefficient and viscosity of a water-glycerol mixture for several glycerol
molar fractions as a function of temperature well inside the metastable supercooled regime. We
perform NMR experiments and verify that the system has at different concentration a fragileto-
strong crossover accompanied by the violation of the Stokes-Einstein relation. We observe
that the crossover temperature depends on the water amount. Studying the fractional representation
of the Stokes-Einstein relation, we find that in these systems dynamical arrest does not
exhibit criticality and the transport parameters have a universal behavior.
Tipologia CRIS:
14.a.1 Articolo su rivista
Keywords:
Vitrification, Metallic Glass, Supercooled Liquid
Elenco autori:
Mallamace, Francesco; Corsaro, Carmelo; Mallamace, Domenico; Vasi, Sebastiano; Vasi, Cirino; Stanley, H. Eugene
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